Product or service details: Specify Description, Quantity, Rate, Amount and Subtotal. The more details you include on the invoice, the better. This way, your client will know exactly what they are paying for upon receiving the invoice. Make sure that your client can understand every item, so that as soon as they receive the invoice, they can pay you instead of asking questions and delaying the process.
Once you've initially saved your invoice, the draft version will have a button to Attach File at the bottom, below the line items and (if applicable) invoice notes.