The best thing about using an invoice system is that you can track your time against the amount you're getting paid for each task. In order to run a successful business, you want your hourly rate to be profitable so you're not losing time and money. Another benefit of using an invoicing system is that you'll never save over an invoice and lose the work you've calculated for another client.
Accurate billing is extremely important when it comes to independent contractors and small business owners. You can't afford to lose a customer over something that should be done right the first time. Business owners who provide detailed, prompt invoices straight to the customer's inbox come out way ahead in the credibility stakes.