Along with the payment terms, you can specify whether you charge a late fee for invoices paid past their due dates. Some freelancers like this option, to enforce getting paid on time. You may also want to include your tax ID number in this area for tax purposes.
Next, you need to specify your payment options — whether you prefer to be paid with cash, a check, a credit card or a service like PayPal. Some companies will offer direct deposit, if you do regular work for them, but more than likely you'll have to send an invoice to request payment every time you complete a project.