When you work out the contract with each client (and yes, you should have a contract in place!), you'll list out the terms of how often you plan to invoice and when you should be paid. For instance, you can agree to bill on the first of each month, or biweekly so you get paid every other Friday. Keep in mind whether your industry is one where you invoice upfront before any work has been completed. In this case you'll be detailing the progress of the project as opposed to doing a monthly invoice.
The client's contact information: Now you'll want to specify who the invoice is being made out to. Include the recipient's name, address, phone number and any other info below the invoice header. Generally, your contact info should be on the opposite side of the recipient's info. So if your business name and logo are on the right side of the invoice at the top, the client's name and info should be below this on the left side.