Once you've initially saved your invoice, the draft version will have a button to Attach File at the bottom, below the line items and (if applicable) invoice notes.
Be transparent – Your client wants to know where their money is going, so don't hide or be too general with line items on your invoices, and be prepared to show receipts. Otherwise, they'll wonder if you're padding the bill. Be specific. For example, instead of listing "materials" as a single expense, list each one on its own line, such as: paint, nails, plywood, etc.