Along with the payment terms, you can specify whether you charge a late fee for invoices paid past their due dates. Some freelancers like this option, to enforce getting paid on time. You may also want to include your tax ID number in this area for tax purposes.
The best thing about using an invoice system is that you can track your time against the amount you're getting paid for each task. In order to run a successful business, you want your hourly rate to be profitable so you're not losing time and money. Another benefit of using an invoicing system is that you'll never save over an invoice and lose the work you've calculated for another client.