Along with the payment terms, you can specify whether you charge a late fee for invoices paid past their due dates. Some freelancers like this option, to enforce getting paid on time. You may also want to include your tax ID number in this area for tax purposes.
For any type of business to succeed, you have to get paid. So whether you do one freelance gig a month or run a full-time writing business, you need to calculate the time you've worked and bill your clients for it.